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Acknowledgements |
6 |
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Contents |
8 |
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About the Author |
10 |
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Abstract |
11 |
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1 Introduction |
12 |
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1.1 Saturated Gaseous Hydrocarbons |
16 |
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1.2 Unsaturated Gaseous Hydrocarbons |
20 |
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1.3 Polymerization of Unsaturated Gaseous Hydrocarbons |
23 |
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1.4 Scope of the Current Volume |
26 |
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References |
27 |
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2 Acetylene |
31 |
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2.1 Edmund Davy and Bicarburet of Hydrogen |
31 |
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2.2 Marcelin Berthelot and Acetylene |
34 |
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2.3 Thomas Willson and Acetylene from Calcium Carbide |
40 |
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References |
45 |
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3 Cuprene |
47 |
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3.1 Berthelot and the Initial Polymerization of Acetylene |
47 |
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3.2 Paul and Arnould Thenard and the Effect of Electric Discharge on Acetylene |
49 |
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3.3 Additional Discharge Studies of Acetylene |
52 |
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3.4 Erdmann and Polymerization Over Copper |
55 |
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3.5 Sabatier and Cuprene |
56 |
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3.6 Alexander and More Studies of Acetylene Over Copper |
58 |
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3.7 Gooch and Further Studies Over Copper Oxide |
59 |
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3.8 Lozani? and a Return to Electric Discharge |
61 |
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3.9 Daniel Berthelot and UV Polymerization |
63 |
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3.10 Kaufmann and Discharge Versus Thermal Polymerization |
64 |
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3.11 Mund and Polymerization via Alpha Particles |
66 |
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3.12 Lind and the Polymerization of Acetylene Under Various Conditions |
68 |
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3.13 What Exactly Is Cuprene? |
70 |
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References |
72 |
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4 Polyenes and Polyvinylenes |
76 |
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4.1 Polyenes |
76 |
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4.1.1 Richard Kuhn and the Study of Conjugated Double Bonds |
77 |
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4.1.2 Blout and the Spectroscopy of Polyenes |
81 |
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4.1.3 Bohlmann and Higher Dimethylpolyenes |
82 |
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4.1.4 Unfunctionalized Polyenes |
84 |
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4.2 Polyvinylenes |
87 |
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4.2.1 Polyvinylenes from Poly(vinyl chloride) |
87 |
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4.2.2 Polyvinylenes from Poly(vinyl alcohol) |
89 |
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References |
90 |
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5 Polyacetylene |
93 |
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5.1 Natta and the Polymerization of Acetylenes |
93 |
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5.2 Additional Studies of Acetylene Polymerizations |
98 |
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5.3 Masahiro Hatano |
100 |
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5.4 Sakuji Ikeda |
104 |
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5.5 Hideki Shirakawa and Polyacetylene Films |
107 |
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References |
114 |
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6 Doped Polyacetylene |
117 |
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6.1 Berets and Smith |
117 |
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6.2 MacDiarmid, Heeger, and (SN)X |
120 |
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6.3 Development of Doped Polyacetylene Films |
123 |
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6.4 Continued Study of Doped Polyacetylene Films |
125 |
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6.5 Naarmann and Efforts to Maximize Conductivity |
126 |
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References |
128 |
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7 2000 Nobel Prize in Chemistry |
133 |
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7.1 Details of the 2000 Nobel Prize in Chemistry |
134 |
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7.2 What Is Discovery? |
135 |
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7.3 Legacy |
138 |
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References |
138 |
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Index |
141 |
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