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Acetylene and Its Polymers - 150+ Years of History
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Acetylene and Its Polymers - 150+ Years of History
von: Seth C. Rasmussen
Springer-Verlag, 2018
ISBN: 9783319954899
144 Seiten, Download: 5339 KB
 
Format:  PDF
geeignet für: Apple iPad, Android Tablet PC's Online-Lesen PC, MAC, Laptop

Typ: A (einfacher Zugriff)

 

 
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Inhaltsverzeichnis

  Acknowledgements 6  
  Contents 8  
  About the Author 10  
  Abstract 11  
  1 Introduction 12  
     1.1 Saturated Gaseous Hydrocarbons 16  
     1.2 Unsaturated Gaseous Hydrocarbons 20  
     1.3 Polymerization of Unsaturated Gaseous Hydrocarbons 23  
     1.4 Scope of the Current Volume 26  
     References 27  
  2 Acetylene 31  
     2.1 Edmund Davy and Bicarburet of Hydrogen 31  
     2.2 Marcelin Berthelot and Acetylene 34  
     2.3 Thomas Willson and Acetylene from Calcium Carbide 40  
     References 45  
  3 Cuprene 47  
     3.1 Berthelot and the Initial Polymerization of Acetylene 47  
     3.2 Paul and Arnould Thenard and the Effect of Electric Discharge on Acetylene 49  
     3.3 Additional Discharge Studies of Acetylene 52  
     3.4 Erdmann and Polymerization Over Copper 55  
     3.5 Sabatier and Cuprene 56  
     3.6 Alexander and More Studies of Acetylene Over Copper 58  
     3.7 Gooch and Further Studies Over Copper Oxide 59  
     3.8 Lozani? and a Return to Electric Discharge 61  
     3.9 Daniel Berthelot and UV Polymerization 63  
     3.10 Kaufmann and Discharge Versus Thermal Polymerization 64  
     3.11 Mund and Polymerization via Alpha Particles 66  
     3.12 Lind and the Polymerization of Acetylene Under Various Conditions 68  
     3.13 What Exactly Is Cuprene? 70  
     References 72  
  4 Polyenes and Polyvinylenes 76  
     4.1 Polyenes 76  
        4.1.1 Richard Kuhn and the Study of Conjugated Double Bonds 77  
        4.1.2 Blout and the Spectroscopy of Polyenes 81  
        4.1.3 Bohlmann and Higher Dimethylpolyenes 82  
        4.1.4 Unfunctionalized Polyenes 84  
     4.2 Polyvinylenes 87  
        4.2.1 Polyvinylenes from Poly(vinyl chloride) 87  
        4.2.2 Polyvinylenes from Poly(vinyl alcohol) 89  
     References 90  
  5 Polyacetylene 93  
     5.1 Natta and the Polymerization of Acetylenes 93  
     5.2 Additional Studies of Acetylene Polymerizations 98  
     5.3 Masahiro Hatano 100  
     5.4 Sakuji Ikeda 104  
     5.5 Hideki Shirakawa and Polyacetylene Films 107  
     References 114  
  6 Doped Polyacetylene 117  
     6.1 Berets and Smith 117  
     6.2 MacDiarmid, Heeger, and (SN)X 120  
     6.3 Development of Doped Polyacetylene Films 123  
     6.4 Continued Study of Doped Polyacetylene Films 125  
     6.5 Naarmann and Efforts to Maximize Conductivity 126  
     References 128  
  7 2000 Nobel Prize in Chemistry 133  
     7.1 Details of the 2000 Nobel Prize in Chemistry 134  
     7.2 What Is Discovery? 135  
     7.3 Legacy 138  
     References 138  
  Index 141  


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